Material Safety Data
Sheet
Sodium Acetate Trihydrate
ACC# 20865
|
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium Acetate Trihydrate
Catalog Numbers: AC123240000, AC123240010, AC217110000,
AC217110010, AC217110025, AC217115000, AC424260000, AC424260010, AC424260030,
AC424260250, S78229, BP334-1, BP334-500, CRNS209-10, NC9796611, NC9923741,
S207-10, S209-10, S209-10LC, S209-3, S209-50, S209-500, S220-1, S607100,
S607212, S60725, S607500, S608-12, S608-3, S608-50, S608-500, S609-12, S609-212,
S609-500, XXS20950KG
Synonyms: Acetic acid, sodium salt, trihydrate.
Company Identification:
Fisher Scientific
1
Reagent Lane
Fair Lawn, NJ
07410
For information, call: 201-796-7100
Emergency
Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
|
Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 6131-90-4 |
Sodium acetate trihydrate |
100 |
unlisted
|
Hazard Symbols: None listed.
Risk Phrases: None listed.
|
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white solid. Caution! May cause eye and skin
irritation. Hygroscopic (absorbs moisture from the air). May cause respiratory
tract irritation.
Target Organs: None.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: Ingestion of large amounts may cause
gastrointestinal irritation.
Inhalation: No hazard expected
in normal industrial use.
Chronic: No information found.
|
Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion: If victim is conscious
and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation: Remove
from exposure and move to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical aid
if cough or other symptoms appear.
Notes to Physician: None
|
Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Combustion generates toxic fumes.
Extinguishing
Media: For small fires, use water spray, dry chemical, carbon dioxide
or chemical foam.
Flash Point: Not applicable.
Autoignition
Temperature: 599 deg C ( 1,110.20 deg F)
Explosion Limits,
Lower:Not available.
Upper: Not available.
NFPA
Rating: (estimated) Health: 1; Flammability: 1; Instability: 0
|
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
|
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation.
Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage: Keep from contact with oxidizing materials. Store
in a cool, dry, well-ventilated area away from incompatible substances. Store
protected from moisture.
|
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Good general ventilation should be sufficient to control
airborne levels.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Sodium acetate trihydrate |
none listed |
none listed |
none listed |
| Sodium acetate anhydrous |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Sodium
acetate trihydrate: No OSHA Vacated PELs are listed for this chemical. Sodium
acetate anhydrous: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear safety glasses with side shields.
Skin: Wear
appropriate gloves to prevent skin exposure.
Clothing: Wear
appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR
1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN
149 approved respirator when necessary.
|
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: odorless
pH: 8.9
(0.1M Solution)
Vapor Pressure: Not available.
Vapor
Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 253 deg F
Freezing/Melting Point:136 deg F
Decomposition
Temperature:Not available.
Solubility: Soluble in water, ether
Specific Gravity/Density:1.45
Molecular
Formula:C2H3O2Na.3H2O
Molecular Weight:136.08
|
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable.
Conditions to Avoid: Exposure to moist air or
water.
Incompatibilities with Other Materials: Strong oxidizers
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
|
Section 11 -
Toxicological Information |
RTECS#:
CAS# 6131-90-4: AJ4580000
CAS# 127-09-3: AJ4300010
LD50/LC50:
Not available.
CAS# 127-09-3:
Draize test,
rabbit, eye: 10 mg Mild;
Draize test, rabbit, skin: 500 mg/24H
Mild;
Inhalation, rat: LC50 = >30 gm/m3/1H;
Oral, mouse: LD50 = 6891
mg/kg;
Oral, rat: LD50 = 3530 mg/kg;
Skin, rabbit: LD50 = >10
gm/kg;
Carcinogenicity:
CAS# 6131-90-4: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 127-09-3: Not listed by ACGIH, IARC,
NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Neurotoxicity: No information
available.
Mutagenicity: Mutagenic effects have occurred in
experimental animals.
Other Studies: No data available.
|
Section 12 -
Ecological Information |
Ecotoxicity: No
data available. Acute aquatic effects (for anhydrous sodium acetate)96-hour
LC50; Fathead minnow: GT 100 mg/L 96-hour LC50; Water flea: GT 1000 mg/L.This
chemical has a high biological oxygen demand, and it is expected to cause
significant oxygen depletion in aquatic systems. It has a low potential to
affect aquatic organisms.
Environmental: This chemical is readily
biodegradable and is not likely to bioconcentrate.
Physical: None
reported
Other: None
|
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 -
Transport Information |
|
US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
|
|
|
No information available. |
| Hazard Class: |
|
|
|
|
|
| UN Number: |
|
|
|
|
|
| Packing Group: |
|
|
|
|
|
|
Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 6131-90-4 is not on the TSCA
Inventory because it is a hydrate. It is considered to be listed if the CAS
number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
CAS#
127-09-3 is listed on the TSCA inventory.
Health & Safety Reporting
List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are
under a Chemical Test Rule.
Section 12b
None of the chemicals are
listed under TSCA Section 12b.
TSCA Significant New Use Rule
None
of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding
RQs
None of the chemicals in this material have an RQ.
SARA
Section 302 Extremely Hazardous Substances
None of the chemicals in this
product have a TPQ.
SARA Codes
CAS # 6131-90-4.
Section
313
No chemicals are reportable under Section 313.
Clean Air
Act:
This material does not contain any hazardous air pollutants. This
material does not contain any Class 1 Ozone depletors. This material does not
contain any Class 2 Ozone depletors.
Clean Water Act:
None of the
chemicals in this product are listed as Hazardous Substances under the CWA. None
of the chemicals in this product are listed as Priority Pollutants under the
CWA. None of the chemicals in this product are listed as Toxic Pollutants under
the CWA.
OSHA:
None of the chemicals in this product are
considered highly hazardous by OSHA.
STATE
CAS# 6131-90-4 is not
present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 127-09-3 is not
present on state lists from CA, PA, MN, MA, FL, or NJ.
California No
Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European
Labeling in Accordance with EC Directives
Hazard Symbols:
Not
available.
Risk Phrases:
Safety Phrases:
S 24/25
Avoid contact with skin and eyes.
WGK (Water
Danger/Protection)
CAS# 6131-90-4: 1
CAS# 127-09-3: 1
Canada -
DSL/NDSL
CAS# 127-09-3 is listed on Canada's DSL List.
Canada -
WHMIS
This product has a WHMIS classification of Not controlled..
Canadian Ingredient Disclosure List
Exposure Limits
|
Section 16 -
Additional Information |
MSDS Creation Date:
7/12/1999
Revision #3 Date: 3/04/2004
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.