Material Safety Data
Sheet
Magnesium oxide
ACC# 13450
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Magnesium oxide
Catalog Numbers: AC193430000, AC193430100, AC205150000,
AC205150025, AC205155000, AC222530000, AC222531000, AC222535000, AC263830000,
AC263830025, AC263835000, AC423890000, AC423890500, AC423895000, S80066,
M300-500, M3494-500, M51-100, M51-500, M68-3
Synonyms: Magnesia.
Company Identification:
Fisher Scientific
1
Reagent Lane
Fair Lawn, NJ
07410
For information, call: 201-796-7100
Emergency
Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 1309-48-4 |
Magnesium oxide |
>95 |
215-171-9 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white powder. Caution! Inhalation of fumes may
cause metal-fume fever. May cause eye irritation. May cause respiratory tract
irritation. Hygroscopic (absorbs moisture from the air).
Target
Organs: Respiratory system, eyes.
Potential Health
Effects
Eye: May cause eye irritation. A
slight irritation of the eyes and nose was observed in 95 workers ex posed to an
unspecified concentration of magnesium oxide dust. (Docume ntation of TLV)
Skin: Dust may cause mechanical irritation. Not absorbed
through the skin. Not irritating to the skin, but use of rigorous washing
procedures to remove dust may cause skin irritation.
Ingestion: No hazard expected in normal industrial use.
Practically non-toxic by ingestion.
Inhalation: Inhalation
of fumes may cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and
increased white blood cell count. Inhalation of dust may cause irritation of the
nose and throat.
Chronic: No information found. Does not
accumulate. Excess magnesium ion is rapidly excreted in the u rine.
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Section 4 - First Aid
Measures |
Eyes: Gently lift eyelids and flush continuously
with water. If irritation develops, get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated
clothing and shoes. Get medical aid if irritation develops and persists. Wash
clothing before reuse.
Ingestion: If swallowed, do not
induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Get medical aid.
Inhalation: If inhaled, remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician: Treat symptomatically
and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Substance is noncombustible. Magnesium oxide, as a fume, is produced when
magnesium is burned in high-temperature processes or exposed to fire conditions.
Extinguishing Media: Use extinguishing media most
appropriate for the surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits,
Lower:Not available.
Upper: Not available.
NFPA
Rating: (estimated) Health: 1; Flammability: 0; Instability: 0
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Avoid generating dusty conditions.
Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Minimize
dust generation and accumulation. Avoid contact with eyes, skin, and clothing.
Use with adequate ventilation. Avoid breathing dust and fume.
Storage: Store in a cool, dry place. Keep away from strong
acids. Store protected from moisture.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate general or local exhaust ventilation to keep
airborne concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Magnesium oxide |
10 mg/m3 TWA (inhalable fraction) |
750 mg/m3 IDLH (fume) |
15 mg/m3 TWA (total
particulate) |
OSHA Vacated PELs:
Magnesium oxide: 10 mg/m3 TWA (total particulate)
Personal
Protective Equipment
Eyes: Wear appropriate
protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Glove protection is not normally required.
Clothing: Wear appropriate protective clothing to minimize
contact with skin.
Respirators: Follow the OSHA respirator
regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Powder
Appearance: white
Odor: odorless
pH:
10.3 (saturated aq soln)
Vapor Pressure: 0 mm Hg @ 25 deg C
Vapor Density: Not available.
Evaporation Rate:Not
available.
Viscosity: Not available.
Boiling Point: 3600
deg C
Freezing/Melting Point:2800 deg C
Decomposition
Temperature:Not available.
Solubility: Very slightly .0086g/100ml
Specific Gravity/Density:3.58
Molecular Formula:MgO
Molecular Weight:40.30
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable at room temperature in closed containers under normal
storage and handling conditions. Absorbs carbon dioxide from the air.
Hygroscopic: absorbs moisture or water from the air.
Conditions to
Avoid: Dust generation, moist air, prolonged exposure to air.
Incompatibilities with Other Materials: Strong acids, interhalogens.
Hazardous Decomposition Products: None.
Hazardous
Polymerization: Will not occur.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 1309-48-4: OM3850000
LD50/LC50:
Not
available.
Carcinogenicity:
CAS# 1309-48-4: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: Controlled human
exposure studies have demonstrated that ma gnesium oxide is less toxic than
other metal oxide fumes o f the same aerodynamic particle size.
Teratogenicity: No data available.
Reproductive Effects:
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
available.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
Not regulated |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 1309-48-4 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
CERCLA
Hazardous Substances and corresponding RQs
None of the chemicals in this
material have an RQ.
SARA Section 302 Extremely Hazardous
Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 1309-48-4 can be found on the following state right to
know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product
are listed.
European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin
and eyes.
WGK (Water Danger/Protection)
CAS# 1309-48-4: 1
Canada - DSL/NDSL
CAS# 1309-48-4 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of Not
controlled..
Canadian Ingredient Disclosure List
CAS# 1309-48-4 is
listed on the Canadian Ingredient Disclosure List.
Exposure
Limits
CAS# 1309-48-4: OEL-ARAB Republic of Egypt:TWA 10 mg/m3
OEL-AUSTRAL
IA:TWA 10 mg/m3 JANUARY 1993 OEL-BELGIUM:TWA 10 mg/m3 JANUARY
1993
OEL-DENMARK:TWA 6 mg/m3 OEL-FRANCE:TWA 10 mg/m3 JANUARY 1993 OEL-G
ERMANY:TWA 6 mg/m3 OEL-GERMANY:TWA 6 mg/m3 JANUARY 1993 OEL-HUNGARY
:TWA
5 mg/m3;STEL 10 mg/m3 OEL-THE NETHERLANDS:TWA 10 mg/m3 JANUARY
1993 OEL-THE
PHILIPPINES:TWA 15 mg/m3 JANUARY 1993 OEL-POLAND:TWA 1
5 mg/m3
OEL-RUSSIA:STEL 5 mg/m3 OEL-SWITZERLAND:TWA 6 mg/m3 OEL-SWI
TZERLAND:TWA 6
mg/m3;STEL 12 mg/m3 JANUAR 1993 OEL-TURKEY:TWA 15 mg/
m3 OEL-UNITED
KINGDOM:TWA 10 mg/m3 JANUARY 1993 OEL-UNITED KINGDOM:
TWA 10 mg/m3 (total
dust) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA c
heck ACGIH TLV OEL IN NEW
ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
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Section 16 -
Additional Information |
MSDS Creation Date:
12/12/1997
Revision #5 Date: 5/25/2004
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.