MSDS Name: Copper (II) Sulfate Anhydrous
Catalog Numbers: C495-500
Synonyms: Copper monosulfate; Cupric sulfate; Cupric sulfate anhydrous; Sulfuric acid, copper(2+) salt (1:1).
Company Identification:
              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Individuals with Wilson's disease are more susceptible to chronic copper poisoning.
Antidote: The use of d-Penicillamine as a chelating agent should be determined by qualified medical personnel.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. U.S. regulations require reporting spills and releases to soil, water and air in excess of reportable quantities.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Copper(II) sulfate	none listed	none listed	none listed

OSHA Vacated PELs: Copper(II) sulfate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties

Physical State: Powder
Appearance: light gray
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:200 deg C
Decomposition Temperature:560 deg C
Solubility: Soluble.
Specific Gravity/Density:3.6
Molecular Formula:CuO4S
Molecular Weight:159.61

Section 10 - Stability and Reactivity

Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: High temperatures, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials: Aqueous solution of copper(2+) sulfate is an acid. Incompatible with strong bases, hydroxylamine, magnesium..
Hazardous Decomposition Products: Oxides of sulfur, copper fumes.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:
CAS# 7758-98-7: GL8800000
LD50/LC50:
CAS# 7758-98-7:
Oral, mouse: LD50 = 369 mg/kg;
Oral, mouse: LD50 = 87 mg/kg;
Oral, rat: LD50 = 300 mg/kg;
Oral, rat: LD50 = 960 mg/kg;
Carcinogenicity:
CAS# 7758-98-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information found.
Teratogenicity: See actual entry in RTECS for complete information.
Reproductive Effects: See actual entry in RTECS for complete information.
Neurotoxicity: No information available.
Mutagenicity: See actual entry in RTECS for complete information.
Other Studies: No information available.

Section 12 - Ecological Information

Ecotoxicity: Fish: Rainbow trout: LC50 = 0.1-2.5 mg/L; 96 Hr; UnspecifiedFish: Bluegill/Sunfish: LC50 = 0.6 mg/L; 48 Hr; 15 mg/L CaCO3Fish: Bluegill/Sunfish: LC50 = 8.0 mg/L; 48 Hr; 68 mg/L CaCO3Fish: Bluegill/Sunfish: LC50 = 10.0 mg/L; 48 Hr; 100 mg/L CaCO3Fish: Bluegill/Sunfish: LC50 = 45.0 mg/L; 48 Hr; 132 mg/L CaCO3 In soil, copper sulfate is partly washed down to lower levels, partly bound by soil components, and partly oxidatively transformed. Copper has a strong affinity for hydrous iron and manganese oxides, clays, carbonate minerals, and organic matter. Sorption to these materials ... suspended in the water column & in the bed sediments, results in relative enrichment of the solid phase and reduction in dissolved levels.
Environmental: Copper is accumulated by plants and animals, but it does not appear to biomagnify from plants to animals. This lack of biomagnification appears common with heavy metals. In air, copper aerosols (in general) have a residence time of 2 to 10 days in an unpolluted atmosphere and 0.1 to > 4 days in polluted, urban areas.
Physical: No evidence was found to indicate that there is any biotransformation process for copper compounds which would have a significant bearing on the fate of copper in aquatic environments.
Other: Has fungicidal properties.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	No information available.				No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7758-98-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

CERCLA Hazardous Substances and corresponding RQs
CAS# 7758-98-7: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7758-98-7: acute.
Section 313
This material contains Copper(II) sulfate (listed as Copper), 97%, (CAS# 7758-98-7) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7758-98-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7758-98-7 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.

Safety Phrases:
S 22 Do not breathe dust.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.

WGK (Water Danger/Protection)
CAS# 7758-98-7: 2
Canada - DSL/NDSL
CAS# 7758-98-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B.
Canadian Ingredient Disclosure List
CAS# 7758-98-7 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 7758-98-7: OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume)
OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume) OEL-AUSTRALIA:TWA 1 mg(Cu)/m3
(dust) OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume) OEL-BELGIUM:TWA 1 mg(Cu
)/m3 (dust) OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume) OEL-DENMARK:TWA 1 m
g(Cu)/m3 (dust) OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume) OEL-FINLAND:TWA
1 mg(Cu)/m3 OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust) OEL-FRANCE:TWA 0.2 m
g(Cu)/m3 (fume) OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust OE
L-GERMANY:TWA 0.1 mg(Cu)/m3 (fume) OEL-GERMANY:TWA 1 mg(Cu)/m3 OEL-G
ERMANY:TWA 1 mg(Cu)/m3 (dust) OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4
mg(Cu)/m3 (dust) OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume) OEL-THE NETHERLA
NDS:TWA 02 mg(Cu)/m3 (fume) OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust
) OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN9 OEL-POLAND:TWA 0
.1 mg(Cu)/m3 (fume) OEL-RUSSIA:STEL 0.5 mg/m3 OEL-RUSSIA:STEL 0.5 pp
m (1 mg(Cu)/m3) (dust) JAN9 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust)
OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (fume) OEL-SWEDEN:TWA 1 mg(Cu)/m3 (tot
al dust) OEL-SWITZERLAND:TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume)
OEL-SWITZERLAND:TWA 1 mg(Cu)/m3;STEL 1 mg(Cu)/m3 OEL-THAILAND:TWA 0.
1 mg(Cu)/m3 (fume) OEL-THAI

Section 16 - Additional Information

MSDS Creation Date: 7/09/1999
Revision #4 Date: 4/23/2002

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.