Material Safety Data
Sheet
Calcium Chloride
ACC# 03900
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Calcium Chloride
Catalog Numbers: S71923, S71924, S79942-1, S79942-2,
S79942-3, C614 10, C614 3, C614 500, C614-10, C614-3, C614-500, C61410, C6143,
C614500, C77 212, C77 500, C77-212, C77-3, C77-500, C77212, C773, C77500,
C77500LC, NC9538916, NC9747663, NC9818597, NC9865903, S79942, S799421, S799422,
S799423, XXC7713KG, XXCALCHL250LB, XXXCALCHL250LB, ZZC772504, ZZC77256
Synonyms: Calpus; Caltac; Dowflake; Liquidow; Peladow; Snowmelt;
Superflake Anhydrous.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 10043-52-4 |
Calcium chloride (cacl2) |
100 |
233-140-8 |
Hazard
Symbols: XI
Risk Phrases: 36
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white powder solid. May be harmful if swallowed. May cause severe
respiratory and digestive tract irritation with possible burns. May cause severe
eye and skin irritation with possible burns. May cause cardiac disturbances.
Hygroscopic. Warning!
Target Organs:
Heart.
Potential Health
Effects
Eye: Contact
with eyes may cause severe irritation, and possible eye burns.
Skin: Contact with skin causes irritation and possible
burns, especially if the skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and
possible burns. May cause cardiac disturbances. May be harmful if swallowed. In
very severe cases, seizures, rapid respiration, slow heartbeat, or death, may
result.
Inhalation: May cause severe irritation of the
upper respiratory tract with pain, burns, and inflammation.
Chronic: Effects may be delayed.
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Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Get medical aid. Immediately flush skin
with plenty of soap and water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious
and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation: Remove
from exposure to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use
mouth-to-mouth resuscitation.
Notes to Physician: Treat
symptomatically and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: Wear appropriate protective clothing to prevent contact
with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent
contact with thermal decomposition products.
Extinguishing
Media: Use extinguishing media most appropriate for the surrounding
fire.
Flash Point: Not applicable.
Autoignition
Temperature: Not applicable.
Explosion Limits, Lower:Not
available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Use with
adequate ventilation. Minimize dust generation and accumulation. Keep container
tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Wash
clothing before reuse. Always use cool water when dissolving Calcium Chloride.
Heat evolved is significant.
Storage: Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture. Store below melting
point.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Calcium chloride (cacl2) |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Calcium
chloride (cacl2): No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear impervious gloves.
Clothing: Wear appropriate protective clothing to minimize
contact with skin.
Respirators: Follow the OSHA respirator
regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white powder
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not
available.
Viscosity: Not available.
Boiling Point: >
1600 deg C @ 760.00mm Hg
Freezing/Melting Point:782 deg C
Decomposition Temperature:Not available.
Solubility:
freely soluble in alcohol
Specific Gravity/Density:2.1500g/cm3
Molecular Formula:CaCl2
Molecular Weight:110.99
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable.
Conditions to Avoid: Dust generation, excess
heat, exposure to moist air or water.
Incompatibilities with Other
Materials: Bromine trifluoride, 2-Furanpercarboxylic Acid, Solutions attack
some metals..
Hazardous Decomposition Products: Hydrogen chloride,
calcium oxide.
Hazardous Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 10043-52-4: EV9800000
LD50/LC50:
CAS#
10043-52-4:
Oral, mouse: LD50 = 1940 mg/kg;
Oral, rat: LD50 = 1
gm/kg;
Carcinogenicity:
CAS# 10043-52-4: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive
Effects: No information found.
Neurotoxicity: No information
found.
Mutagenicity: Mutagenic effects have occurred in experimental
animals.
Other Studies: See actual entry in RTECS for complete
information.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 10043-52-4 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 10043-52-4: acute, chronic, reactive.
Section
313
No chemicals are reportable under Section 313.
Clean Air
Act:
This material does not contain any hazardous air pollutants. This
material does not contain any Class 1 Ozone depletors. This material does not
contain any Class 2 Ozone depletors.
Clean Water Act:
None of the
chemicals in this product are listed as Hazardous Substances under the CWA. None
of the chemicals in this product are listed as Priority Pollutants under the
CWA. None of the chemicals in this product are listed as Toxic Pollutants under
the CWA.
OSHA:
None of the chemicals in this product are
considered highly hazardous by OSHA.
STATE
CAS# 10043-52-4 is not
present on state lists from CA, PA, MN, MA, FL, or NJ.
California No
Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European
Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36 Irritating to eyes.
Safety
Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
WGK (Water Danger/Protection)
CAS# 10043-52-4: 0
Canada
- DSL/NDSL
CAS# 10043-52-4 is listed on Canada's DSL List.
Canada
- WHMIS
This product has a WHMIS classification of D2B.
Canadian
Ingredient Disclosure List
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
12/12/1997
Revision #5 Date: 11/19/2001
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.