Material Safety Data
Sheet
Tert.-Amyl Alcohol
ACC# 22860
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Tert.-Amyl Alcohol
Catalog Numbers: AC166620200, A730 1, A730-1, A7301,
NC9025733, NC9092369, NC9142334, NC9172140, NC9981307, XXA730200LI/T,
XXA730200LIX, XXA73020LI, XXA730P20LI
Synonyms: tert-Pentanol;
2-Butanol, 2-Methyl; Ethyl Dimethyl Carbinol; 3-Methylbutan-3-ol; Amylene
Hydrate, 2-methyl-2-butanol
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 75-85-4 |
2-Methyl-2-Butanol |
100 |
200-908-9 |
Hazard
Symbols: XN F
Risk Phrases: 11 21/22
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 20 deg C.
Warning! Flammable liquid and vapor. May be harmful
if swallowed. May cause eye and skin irritation. May cause central nervous
system depression. Light sensitive. May cause respiratory tract irritation. May
be harmful if absorbed through the skin.
Target Organs:
Central nervous system.
Potential Health
Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. Prolonged and/or repeated
contact may cause defatting of the skin and dermatitis. May be harmful if
absorbed through the skin.
Ingestion: May cause central
nervous system depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause collapse,
unconsciousness, coma and possible death due to respiratory failure. May be
harmful if swallowed.
Inhalation: May cause central nervous
system effects including vertigo, anxiety, depression, muscle incoordination,
and emotional instability. May cause effects similar to those described for
ingestion. May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid if irritation develops or persists.
Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion: Do not induce vomiting. If victim is conscious
and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from
exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician: Treat symptomatically
and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Vapors can travel to a source of ignition and flash back. During a fire,
irritating and highly toxic gases may be generated by thermal decomposition or
combustion. Use water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread by the use
of water. Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Containers may
explode if exposed to fire.
Extinguishing Media: For small
fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
Water may be ineffective. For large fires, use water spray, fog or
alcohol-resistant foam. Do NOT use straight streams of water. Cool containers
with flooding quantities of water until well after fire is out.
Flash
Point: 20 deg C ( 68.00 deg F)
Autoignition Temperature: 435 deg
C ( 815.00 deg F)
Explosion Limits, Lower:1.30 vol %
Upper: 9.60 vol %
NFPA Rating: (estimated)
Health: 1; Flammability: 3; Instability: 0
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spill with inert material
(e.g. vermiculite, sand or earth), then place in suitable container. Avoid
runoff into storm sewers and ditches which lead to waterways. Clean up spills
immediately, observing precautions in the Protective Equipment section. Remove
all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor
suppressing foam may be used to reduce vapors.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation.
Avoid contact with skin and eyes. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Do not ingest or inhale. Prevent
build up of vapors to explosive concentration. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage: Keep away from heat, sparks, and flame.
Store in a cool, dry place. Flammables-area. Keep containers tightly closed.
Store protected from light.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| 2-Methyl-2-Butanol |
none listed |
none listed |
none
listed |
OSHA Vacated PELs:
2-Methyl-2-Butanol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear appropriate
protective clothing to prevent skin exposure.
Respirators: A
respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2
requirements or European Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Liquid
Appearance: clear, colorless
Odor: camphor
pH: Not available.
Vapor Pressure: 10 mm Hg
Vapor
Density: 3.0
Evaporation Rate:Not available.
Viscosity: 3.7 mPas 25 deg C
Boiling Point: 102 deg C @
760.00mm Hg
Freezing/Melting Point:-12 deg C
Decomposition
Temperature:Not available.
Solubility: SOLUBLE IN WATER: 120 G/L
(20°C)
Specific Gravity/Density:.8050g/cm3
Molecular
Formula:C5H12O
Molecular Weight:88.15
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: High temperatures, incompatible materials, ignition sources,
excess heat, exposure to flame.
Incompatibilities with Other
Materials: Strong oxidizing agents.
Hazardous Decomposition
Products: Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 75-85-4: SC0175000
LD50/LC50:
CAS#
75-85-4:
Oral, rabbit: LD50 = 2028 mg/kg;
Oral, rat: LD50 = 1
gm/kg;
Oral, rat: LD50 = 1000 mg/kg;
Carcinogenicity:
CAS# 75-85-4: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Neurotoxicity: No information
available.
Mutagenicity: No information available.
Other
Studies: See actual entry in RTECS for complete information.
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Section 12 -
Ecological Information |
Ecotoxicity: No
data available. No information available.
Environmental: Terrestrial:
High volatility, high mobility in soil. Aquatic: High volatility. Atmospheric:
Exists as vapor, half-life 3.3 days. Biodegradation slight and low
bioconcentration potential.
Physical: No information available.
Other: For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
PENTANOLS |
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No information available. |
| Hazard Class: |
3 |
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| UN Number: |
UN1105 |
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| Packing Group: |
II |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 75-85-4 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
CERCLA
Hazardous Substances and corresponding RQs
None of the chemicals in this
material have an RQ.
SARA Section 302 Extremely Hazardous
Substances
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 75-85-4: flammable.
Section 313
No chemicals
are reportable under Section 313.
Clean Air Act:
This material
does not contain any hazardous air pollutants. This material does not contain
any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA. None of the chemicals in this
product are listed as Priority Pollutants under the CWA. None of the chemicals
in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly
hazardous by OSHA.
STATE
CAS# 75-85-4 can be found on the
following state right to know lists: Pennsylvania, Massachusetts.
California
No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European
Labeling in Accordance with EC Directives
Hazard Symbols:
XN F
Risk Phrases:
R 11 Highly flammable.
R 21/22 Harmful in
contact with skin and if
swallowed.
Safety Phrases:
S 16
Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact
with skin and eyes.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 75-85-4: 1
Canada -
DSL/NDSL
CAS# 75-85-4 is listed on Canada's DSL List.
Canada -
WHMIS
This product has a WHMIS classification of B2, D2B.
Canadian
Ingredient Disclosure List
Exposure Limits
CAS# 75-85-4:
OEL-DENMARK:TWA 100 ppm (360 mg/m3)
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Section 16 -
Additional Information |
MSDS Creation Date:
3/02/1998
Revision #3 Date: 3/18/2003
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.